姓名:张慧君 .jpg)
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专业:有机化学
电话:010-62759643
教育背景:
2004,7 至今
北京大学化学与分子工程学院有机化学博士研究生导师:席振峰教授
2000,7 — 2004,9
郑州大学化学系有机化学专业本科,并获理学学士学位
研究方向:
1.新型多取代环戊二烯基钌配合物的设计和合成,以及其在催化反应中的应用。
2.1,1,4,4-四卤代-1,3-丁二烯化合物的合成和应用研究。
发表论文:
1.Hui-jun Zhang, Bernard Demerseman, Zhenfeng Xi, Christian Bruneau. Ruthenium Complexes Bearing Bulky Pentasubstituted Cyclopentadienyl Ligands and Evaluation of [Ru( 5-C5Me4R)(MeCN)3][PF6] Precatalysts in Nucleophilic Allylic Substitution Reactions. Eur. J. Inorg. Chem. 2008, 3212–3217
2.Hui-jun Zhang, Bernard Demerseman, Christian Bruneau* and Zhenfeng Xi*. [Ru(ɳ5-C5Me4R)(2-quinolinecarboxylato)(ɳ3-allyl)][PF6] Ruthenium Complexes as Performing Catalysts for Regioselective Nucleophilic Allylic Substitution. Adv. Synth. Catal. submitted
3.Hui-jun Zhang, Zhiyi Song, Chao Wang, Christian Bruneau* and Zhenfeng Xi*. Synthesis of stereo-defined 1,1,4,4-tetrahalo- and 1,1,4,4-mixed-tetrahalo-1,3-butadienes. Tetrahedron Lett. 2008, 49, 624.
4.Qiaoshu Hu, Dongzhen Li, Huijun Zhang, and Zhenfeng Xi*. A novel reaction of titanacyclopentenes and aldehydes with or without Lewis acids. Tetrahedron Lett. 2007, 48, 6167.
5. Hui-Jun Zhang, Bernard Demerseman, Loic Toupet, Zhenfeng Xi,* and Christian Bruneau* Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from β-Silylated Allylic Carbonates Organometallics 2009, 28, ASAP online
6. Zhang, H. -J.; Meng, T.; Demerseman, B.; Bruneau, C.; Xi, Z.* Hydride-induced Novel Cyclization of Dienedinitriles Leading to Multi-functionalized Cyclopentadienes. Org. Lett. 2009, ASAP online.
7. Hui-Jun Zhang, Bernard Demerseman, Zhenfeng Xi,* and Christian Bruneau* Ruthenium Catalysts for Structurally Controlled Mono- and Bis-Allylation of Active Methylene Compounds with Aliphatic Allylic Substrates. Adv. Synth. Catal. 2009, accepted.