姓名：张韶光
专业：有机化学
电话：010-62759643
电子邮件：conanheji@hotmail.com
教育背景：
2008.9 —
北京大学化学与分子工程学院有机化学专业硕博生
导师：席振峰教授、张文雄副教授
2004.9 — 2008.7
北京理工大学化工与环境学院制药工程专业本科生
导师：周智明教授（北京理工大学）；席振峰教授、张文雄副教授（毕业论文）
研究方向：
1. 二茂锆促进二炔基硅烷与腈偶联环化反应及机理研究
2. 氮杂半瞬烯化学
发表论文：
Research Papers:
1. Lewis Acid-Catalyzed Site-Selective Cycloadditions of 2,6-Diazasemibullvalenes with Isocyanides, Azides and Diazo Compounds: Novel Reaction Patterns Leading to Diaza- and Triaza-Brexadiene Derivatives.
Shaoguang Zhang, Wen-Xiong Zhang and Zhenfeng Xi*. Angew. Chem. Int. Ed. 2013, doi: 10.1002/anie.201210126.
2. 2,6-Diazasemibullvalenes: Synthesis, Structural Characterization, Theoretical Analysis and Reaction Chemistry.
Shaoguang Zhang, Junnian Wei, Ming Zhan, Qian Luo, Chao Wang, Wen-Xiong Zhang and Zhenfeng Xi*. J.Am. Chem. Soc. 2012, 134, 11964–11967. (Selected as JACS Spotlight: J. Am. Chem. Soc. 2012, 134, 13533–13534)
3. One-pot Synthesis of Pyrrolo[3,2-d]pyridazines and Pyrrole-2,3-diones via Zirconocene-mediated Four-component Coupling of Si-tethered Diyne, Nitriles and Azide.
Shaoguang Zhang, Jing Zhao, Wen-Xiong Zhang and Zhenfeng Xi*. Org. Lett. 2011, 13, 1626-1629.
4. One-Pot Selective Syntheses of 5-Azaindoles through Zirconocene-Mediated Multicomponent Reactions with Three Different Nitrile Components and One Alkyne Component.
Shaoguang Zhang, Wen-Xiong Zhang, Jing Zhao and Zhenfeng Xi*. Chem. Eur. J. 2011, 17, 2442-2449.
5. Cleavage and Reorganization of Zr−C/Si−C Bonds Leading to Zr/Si−N Organometallic and Heterocyclic Compounds.
Shaoguang Zhang, Wen-Xiong Zhang, Jing Zhao and Zhenfeng Xi*. J.Am. Chem. Soc. 2010, 132, 14042-14045.
6. Efficient One-Pot Synthesis of N-Containing Heterocycles by Multicomponent Coupling of Silicon-Tethered Diynes, Nitriles, and Isocyanides through Intramolecular Cyclization of Iminoacyl-Zr Intermediates.
Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. Chem. Eur. J. 2010, 16, 8419-8426. (VIP Paper)
7. One-pot Multi-Component Synthesis of Azaindoles and Pyrroles from One Molecule of silicon-Tethered Diyne and Three or Two Molecules of Organonitriles Mediated by Zirconocence.
Shaoguang Zhang, Xiaohua Sun, Wen-Xiong Zhang, and Zhenfeng Xi*. Chem. Eur. J. 2009, 15, 12608-12617.
8. Zirconium- and Silicon-Containing Intermediates with Three Fused Rings in a Zirconocene-Mediated Intermolecular Coupling Reaction.
Wen-Xiong Zhang (Assoc. Prof. of the group), Shaoguang Zhang, Xiaohua Sun, Masayoshi Nishiura, Zhaomin Hou,* and Zhenfeng Xi*. Angew. Chem. Int. Ed. 2009, 48, 7227-7231.
9. Reactivity of Seven-membered Azazirconacycloallenes and Four-membered Zirconacycles towards Diphenylacetonitrile
Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*. Organometallics 2012, 37, 8370-8374.
10. Synthesis of Benzothieno[2,3-b]thiophenes, [2,3-b:3,2-d]-dithienothiophenes and Their Selenium Derivatives via Electrophilic Cyclization and McMurry Cyclization
Weizhi Geng, Zitao Wang, Hanliu Wang, Shaoguang Zhang, Wen-Xiong Zhang and Zhenfeng Xi*. Tetrahedron 2012, 68, 5283-5289.
11. Palladium-catalyzed Synthesis of Benzosilolo[2,3-b]indoles via Cleavage of C(sp3)-Si Bond and Consequent Intramolecular C(sp2)-Si Coupling.
Yun Liang, Shaoguang Zhang,and Zhenfeng Xi*. J. Am. Chem. Soc. 2011, 133, 9024-9027.
12. Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile.
Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*. Organometallics 2011, 30, 3464-3467.
13. Synthesis of Benzothiophene Derivatives from Dilithio Reagents, Sulfur, and Electrophiles via Electrophilic Cyclization.
Zitao Wang, Weizhi Geng, Hanliu Wang, Shaoguang Zhang, Wen-Xiong Zhang and Zhenfeng Xi*. Tetrahedron Lett. 2011, 52, 6997-6999.
14. Iterative Dianion Relay Along the Ring: Formation of gem-Bis(trimethylsilyl) Cyclopentenones from 2,5-Bis(trimethylsilyl) Oxy-cyclopentadienyl Dianions and Acid Chlorides.
Heng Li, Lantao Liu, Zitao Wang, Fei Zhao, Shaoguang Zhang,Wen-Xiong Zhang and Zhenfeng Xi*. Chem. Eur. J. 2011, 17, 7399-7403.
15. One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)2.
Dongzhen Li, Yang Wang, Wen-Xiong Zhang,* Shaoguang Zhang,Jie Guang, and Zhenfeng Xi*. Organometallics 2011, 30, 5278-5283.
16. Star-shaped Silacyclobutene-Containing π-Systems: Synthesis and Optical Properties
Junhui Liu, Shaoguang Zhang,Wen-Xiong Zhang,and Zhenfeng Xi*. Organometallics 2009, 28, 413-417.
Reviews:
17. Zirconocene & Si-tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis.
Wen-Xiong Zhang (Assoc. Prof. of the group), Shaoguang Zhang, and Zhenfeng Xi*. Acc. Chem. Res. 2011, 44, 541-551.
18. SiMe3-Substituted 1,3-Butadienes for the Diels-Alder Reaction, the Ene reaction, and the Allylation Reaction.
Fei Zhao, Shaoguang Zhang,and Zhenfeng Xi*. Chem. Comm. 2011, 47, 4348-4357.
19. Powerful Tools toward Complex Organic Molecules-Highlight on 2010 Nobel Prize on Chemistry.
Shaoguang Zhang,Wen-Xiong Zhang*. University Chem. 2010, 6, 1-5.
20. Reactivity of Six-Membered Silacycles.
Shaoguang Zhang, Junhui Liu, Wen-Xiong Zhang, and Zhenfeng Xi*. Prog. Chem. 2009, 21, 1487-1493.
21. Synthesis of Six-Membered Silacycles.
Junhui Liu, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. Prog. Chem. 2009, 21, 1475-1486.
奖励：
北京理工大学2005-2006年度SMC奖学金
北京理工大学2005-2006年度共青团系统"团员之星"
北京理工大学2006-2007学年优秀学生标兵
2010 ICCEOCA-5/NICCEOCA-1 0th Junior ACP Conference Oral Award
2010年第二届陶氏化学可持续发展创新大赛优秀奖
2010年北京大学常青奖学金
2011年北京大学校长奖学金
2011年北京大学“学术十杰”
2011年北京大学化学学院首届“化学之星”特等奖
2012年研究生国家奖学金