姓名:梁云
专业:有机化学
电话:010-62759643
邮箱:
liangyun1972@126.com
 
主要教育和工作经历:
 
2009年7月-      北京大学化学学院博士后(导师:席振峰 教授)
2008年11月      被聘为湖南师范大学化学化工学院副教授
2007年6月       获湖南师范大学理学博士学位(导师:李金恒教授)
2005年6月       获湖南师范大学工学硕士学位(导师:李金恒教授)
1994年6月       获湖南师范大学化学教育学士学位
 
研究领域和兴趣:
 
炔烃的卤钯化反应研究
过渡金属催化的偶联反应及串联反应研究
基于邻三甲基硅芳基磺酸酯为芳炔前体的应用研究
 
获奖情况:
 
硕士毕业论文评为湖南省优秀硕士毕业论文
博士毕业论文评为湖南师范大学优秀博士毕业论文
 
发表论文:
 
 

1. Liu, Y.-L.; Liang, Y.;* Pi, S.-F.; Li, J.-H.*, Selective Synthesis of o-Acylbenzylphosphonates by Insertion Reactions of Arynes into β-Ketophosphonates, J. Org. Chem., Articles ASAP. DOI: 10.1021/jo900847u.

2. Pi, S.-F.; Tang, B.-X.; Yin, D.-L.; Li, J.-H.*; Liu, Y.-L.; Liang, Y.*, Palladium-Catalyzed Decarboxylative Coupling of Allylic Alkynoates with Arynes, Org. Lett., 2009, 11, 2309.

3. Liu, Y.-L.; Liang, Y.;* Pi, S.-F.; Huang, X.-C.; Li, J.-H.*, Palladium-Catalyzed Cocyclotrimerization of Allenes with Arynes: Selective Synthesis of Phenanthrenes, J. Org. Chem, 2009, 74, 3199.

4. Huang, X.-C.; Wang, F.; Liang, Y.;* Li, J.-H.*, Halopalladation/Decarboxylation/Carbon-Carbon Forming Domino Process: Synthesis of 5-Halo-6-substituted Benzo[b]naphtho[2,1-d]furans, Org. Lett., 2009, 11, 1139.

5. Peng, P.; Tang, B.-X.; Pi, S.-F.; Liang, Y.; Li, J.-H.*, Synthesis of (E)-3-(Isobenzofuran-3(1H)-ylidene)indolin-2-ones by the Palladium-Catalyzed Intramolecular C−H Functionalization Process, J. Org. Chem., 2009, 74, 3569.

6. Huang, X.-C.; Liu, Y.-L.; Liang, Y.;* Pi, S.-F.; Wang, F.; Li, J.-H.*, Cycloaddition of Arynes with Iodonium Ylides: A Mild and General Route for the Synthesis of Benzofuran Derivatives, Org. Lett. 2008, 10, 1525.

7. Xie, Y.-X.; Wang, J.; Li, J.-H.*; Liang, Y.*, Reusable and Ligand-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Halides with Arylboronic Acids in Tetra-n-butylammonium Bromide, Chinese Journal of Chemistry, 2008, 26, 2261.

8. Liang, Y.; Tao, L.-M.; Zhang, Y.-H.; Li, J.-H.*, Palladium-Catalyzed Cross-Coupling Reactions of 1,2-Diiodoalkenes with Terminal Alkynes: Selective Synthesis of Unsymmetrical Buta-1,3-diynes and 2-Ethynylbenzofurans, Synthesis. 2008, 3988.

9. Tang, B.-X.; Tang, D.-J.; Tang, S.; Yu , Q.-F.; Zhang, Y.-H.; Liang, Y.; Zhong, P.; Li, J.-H.* Selective Synthesis of Spiro[4,5]trienyl Acetates via An Intramolecular Electrophilic ipso-Iodocyclization Process, Org. Lett. 2008, 10, 1063.

10. Tang, S.; Peng, P.; Pi, S.-F.; Liang, Y.; Wang, N.-X.; Li, J.-H.* Sequential Intermolecular Aminopalladation/ortho-Arene C-H Activation Reactions of N-Phenylpropiolamides with Phthalimide Copper/Silver-Cocatalyzed Conia-Ene Reaction of Linear b-Alkynic -Ketoesters, Org. Lett. 2008, 10, 1179.

11. Liang, Y.; Xie, Y.-X.; Li, J.-H.* Cy2NHHX-Promoted Cyclizations of o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoate with Copper Halides to Synthesize Isocoumarins and -Pyrone, Synthesis. 2007, 3, 400.

12. Li, J.-H.*; Zhang, Y.-H.; Song, R.-J.; Xie, Y.-X.; Deng, C.-L.; Liang, Y. -Keto Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction, Synthesis 2007, 2957.

13. 陶李明,梁云,李金恒*,末端炔烃二聚反应合成共轭烯炔的研究进展,有机化学2007271078.

14. Liang, Y.; Tang, S.; Zhang, X.-D.; Mao, L.-Q.; Xie, Y.-X.; Li, J.-H.* Novel and Selective Palladium-Catalyzed Annulations of 2-Alkynylphenols To Form 2-Substituted 3-Halobenzo[b]furans, Org. Lett. 2006, 8, 3017.

15. Liang, Y.; Xie, Y.-X.; Li, J.-H.* General and Modified Palladium-Catalyzed Sonogashira Cross-Coupling Reaction under Copper-, Amine- and Solvent-Free Conditions, J. Org. Chem. 2006, 71, 379.

16. Li, J.-H.*; Tang, B.-X.; Tao, L.-M.; Liang, Y.; Zhang, M.-B. Reusable Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Organotins in Inexpensive Ionic Liquids, J. Org. Chem. 2006, 71, 7488.

17. Liu, W.-J.; Xie, Y.-X.; Liang, Y.; Li, J.-H.* Reusable and Efficient Pd(OAc)2/TBAB/PEG-400 System for Suzuki-Miyaura Cross-Coupling Reaction Under Ligand-Free Conditions, Synthesis. 2006, 860.
18. Li, J.-H.*; Hu, X.-C.; Liang, Y.; Xie, Y.-X. PEG-400 Promoted Pd(OAc)2/DABCO-Catalyzed Cross-Coupling Reaction in Aqueous Media, Tetrahedron. 2006, 62, 31-38.
19. 王德平,张旭东,梁云,李金恒*,钯催化Stille交叉偶联反应研究新进展,有机化学20062619.
20. Li, J.-H.*; Liang, Y.; Wang, D.-P.; Liu, W.-J.; Xie, Y.-X.; Yin, D.-L. Efficient Stille Cross-Coupling Reaction Catalyzed by Pd(OAc)2/Dabco Catalytic System, J. Org. Chem. 2005, 70, 2832.
21. Li, J.-H.*; Liang, Y.; Xie, Y.-X. Efficient Palladium-Catalyzed Homocoupling Reaction and Sonogashira Cross-Coupling Reaction of Terminal Alkynes under Aerobic Conditions. J. Org. Chem. 2005, 70, 4393.
22. Li, J.-H.*; Zhu, Q.-M.; Liang, Y.; Yang D. Efficient and Reusable PdCl2(MeCN)2/CuCl2/PEG-400 System for Cyclization of Alkenyl –Keto Esters and Amides, J. Org. Chem. 2005, 70, 5347.
23. Li, J.-H.*; Liang, Y.; Zhang, X.-D. Amine- and phosphine-free palladium(II)-catalyzed homocoupling reaction of ter minal alkynes, Tetrahedron. 2005, 61, 1903.
24. Li, J.-H.*; Liang, Y.; Xie, Y.-X. Efficient Stille Cross-Coupling Reaction Catalyzed by Pd(OAc)2/DAB-Cy Catalytic System, Tetrahedron. 2005, 61, 7289.
25. 梁云,李金恒*,钯催化Ullamnn偶联反应研究,有机化学200525147
26. 李金恒*,刘文杰,梁云,谢叶香,硫酸亚铈催化的芳香化合物与苄基醇、烯丙醇类化合物以及苄基氯的傅-克烷基化反应研究,有机化学2005251045
27. 李金恒*,廖华,梁云,尹笃林,二氧化碳促进的醛和酮等羰基化合物烯丙基化反应研究,有机化学2005251591
28. 梁云,唐石,张旭东,谢叶香, 李金恒*,基于卤化钯与炔烃加成反应所形成C-Pd -键的应用研究,有机化学200525 (Suppl. 1)207
29. 谢叶香,刘文杰,梁云,王德平,张旭东,胡惜朝,邓辰亮,李金恒*,叔胺作为配体在钯催化交叉偶联反应中应用研究,有机化学200525 (Suppl. 1)209
30. Li, J.-H.*; Liang, Y.; Xie, Y.-X. Mild and Selective Palladium-Catalyzed Dimerization of Terminal Alkynes To Form (Z,Z)-1,4-Dihalo-1,3-dienes, J. Org. Chem. 2004, 69, 8125.
31. Li, J.-H.*; Liang, Y.; Liu, W.-J.; Tang, S.; Xie, Y.-X. Ammonium Chloride Promoted Palladium-Catalyzed Ullmann Coupling of Aryl Bromides, Chin. J. Chem. 2004, 22, 1421.
32. 唐石,梁云,刘文杰,李金恒*,氯化钯催化的交叉偶联反应,有机化学2004241133
33. 刘文杰,唐石,梁云,李金恒*,超临界二氧化碳介质中过渡金属催化有机反应新进展,有机化学2004241553