张文雄  教授，博士生导师

  

►研究领域：稀土金属有机化学、有机合成化学

►讲授课程：本科生«综合化学实验» （主讲）

研究生«合成化学II» （主讲）

电话：010-6275-8294

传真：010-6275-1708

电子信箱：wx_zhang@pku.edu.cn

 

►主要教育和工作经历：

2016.08-至今   北京大学化学学院教授

2009.10-2009.12  日本理化学研究所客座研究员

2008.05                 被聘为博士生导师

2007.10-2016.07   北京大学化学学院副教授

2004.11-2007.09  日本理化学研究所博士后（导师：侯召民 教授）

2004.01-2004.03 日本北海道大学JST研究员（导师：高桥保 教授）

2002.10-2004.10  北京大学化学学院博士后（导师：席振峰 教授）

2003.01                  获南开大学理学博士学位（导师：宋礼成 院士）

1999.06                 获广西师范大学理学硕士学位（导师：黄文榜 教授）

1996.07                 获湖南师范大学化学教育学士学位

 

►部分社会服务与学术任职：

  • 2014- «中国化学快报»青年编委会委员
  •  
  • 2011- 教育部留学回国人员科研启动基金评审专家
  •  
  • 2011- 国家出版基金项目《化学大词典》有机化学学科编委

 

►部分荣誉及奖励：

    • 2010年和2013年，获北京大学东圣奖教金

    • 2010-2012年，获北京大学专业技术岗位青年人才支持计划

    • 2015年，获Thieme Chemistry Journals Award

 

►部分国内外学术会议的邀请报告：

  1. 2008年10月20日-23日，南京，中国化学会第十五届全国金属有机化学学术讨论会，题目：1，4-二锂-1，3-丁二烯衍生物的分离和单晶结构分析；（口头邀请报告）
  2. 2008年11月14日-15日，北京，第六届北大-南开-化学所有机化学沙龙, 题目：金属促进或催化反应中活性金属有机中间体的分离及机理探讨；（邀请报告）
  3. 2009年7月10日-14日，张家界，The 5th China-Korea Symposium on Organic Chemistry，题目：Isolation and Application of Active Intermediates in Catalytic Addition Reaction of Amines to Carbodiimides；（邀请报告）
  4. 2009年8月17日-20日，西安，中国化学会第六届全国有机化学学术会议，题目：胺对碳二亚胺催化加成反应中重要中间体的分离和合成应用；（口头邀请报告）
  5. 2010年5月29日，北京，2010 GCOE and 111 Program: Peking University & Hokkaido University Joint Seminar on Organometalic Chemistry and Organic Syntheses，题目：Novel Carbodiimide Chemistry: C=N Double Bond Cleavage and sp3 C-H Bond Functionalization；（邀请报告）
  6. 2010年6月5日，桂林，广西师范大学，题目：活性金属有机化合物的分离及反应机理探讨；（邀请报告）
  7. 2010年10月22日-25日，浙江温州，中国化学会第十六届全国金属有机化学学术讨论会，题目：碳二亚胺新反应化学及机理探讨，（口头邀请报告）
  8. 2011年1月10-13日，北京，First RCUK China Funded UK-China Workshop on Metals in Organic Synthesis: Toward Cleaner, Greener Chemical Processes，题目：Metal-promoted Novel Carbodiimide  Chemistry and Mechanistic Investigation；（邀请报告）
  9. 2011年9月1-5日，北京，The 1st Symposium on “New Frontiers in Organic Chemistry: Towards Cleaner, Greener Chemical Processes”，题目：Metal-promoted Novel Carbodiimide Chemistry and Mechanistic Investigation；（邀请报告）
  10. 2011年11月12-15日，南京，中国化学会第七届全国有机化学学术会议，题目：金属促进或催化的碳二亚胺反应化学及机理探讨；（口头邀请报告）
  11. 2011年10月24日，武汉，武汉理工大学，题目：金属参与的碳二亚胺反应化学及机理探讨；（邀请报告）
  12. 2011年10月25日，武汉，华中师范大学，题目：金属参与的碳二亚胺反应化学及机理探讨；（邀请报告）
  13. 2011年12月19日，广州，华南理工大学，题目：碳二亚胺的新反应化学及机理探讨；（邀请报告）
  14. 2012年7月15-18日，北海道，日本，Peking University & Hokkaido University Joint Seminar on Organometalic Chemistry and Organic Syntheses，题目：Mechanism-based Organic and Organometallic Chemistry of Carbodiimides；（邀请报告）
  15.  2012年9月15-20日，莫斯科，俄罗斯，The International Conference "Catalysis in Organic Synthesis" (ICCOS-2012)，题目：Mechanism-based Organic and Organometallic Chemistry of Carbodiimides；（口头邀请报告）
  16. 2012年11月1-4日，首尔，韩国，The ISOMC (International Symposium on Organometallic Chemistry)，题目：Mechanism-based Organic and Organometallic Chemistry of Carbodiimides；（邀请报告）
  17. 2012年11月13日，长沙，湖南师范大学，题目：基于机理和金属有机活性中间体的碳二亚胺化学；（邀请报告）
  18. 2013年3月23-25日，京都，日本，The 3rd CCS-CSJ Young Chemists Forum，题目：Mechanism-directed Organic and Organometallic Chemistry of Carbodiimides；（邀请报告） 

 

►主要科学研究基金项目：

♦ 正在承担项目：

  • 国家自然科学基金委员会面上项目1项（主持）
  • 国家科技部973项目子课题2项（参与）
  • 南开大学元素有机国家重点实验室开放基金1项（主持）

♦ 已结题项目：

  • 国家自然科学基金委员会青年基金项目1项（主持）
  • 教育部留学回国人员科研启动基金1项（主持）
  • 国家自然科学基金委员会面上项目1项（主持）
  • 国家自然科学基金委员会创新研究群体1项（参与）

  

发表论文：

  • 77. Yang Wang, Yue Chi, Fei Zhao, Wen-Xiong Zhang*, and Zhenfeng Xi. ″Synthesis, Characterization, and Reactivity of N-Acyl Chloroformamidines: Useful Building Blocks for Construction of N-Acyl Ureas, Thioureas, Amidines and 1,1-Diaminoethylene″. Synthesis 2013, 45, 347-354. 
  • 76. Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Lewis Acid-Catalyzed Site-Selective Cycloadditions of 2,6-Diazasemibullvalenes with Isocyanides, Azides and Diazo Compounds: Novel Reaction Patterns Leading to Diaza- and Triaza-Brexadiene Derivatives″. Angew. Chem. Int. Ed. 2013, 52, ASAP. 
  • 75. Junnian Wei, Zitao Wang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Construction of Octaalkyl- Substituted and Decasubstituted all-cis-Octatetraenes via Linear Dimerization of 1,4-Dicopper-1,3-butadienes and Subsequent Cross-coupling with Halides″. Org. Lett. 2013, ASAP.

 

2012

  • 74. Yang Wang, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi.* ″Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides″. J. Am. Chem. Soc. 2012, 134, 2926-2929. 
  • 73. Ling Xu, Zitao Wang, Wen-Xiong Zhang*, and Zhenfeng Xi*. ″Rare-Earth Metal Tris(trimethylsilylmethyl) Anionic Complexes Bearing One 1-Phenyl-2,3,4,5-tetrapropylcyclopentadienyl Ligand: Synthesis, Structural Characterization and Application″. Inorg.Chem. 2012, 51, 11941–11948. 
  • 72. Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang,* and Zhenfeng Xi*. ″Reactivity of Seven-membered Azazirconacycloallenes and Four-membered Zirconacycles towards Diphenylacetonitrile″. Organometallics 2012, 31, 8370–8374. 
  • 71. Fei Zhao, Yang Wang, Wen-Xiong Zhang*, and Zhenfeng Xi*. ″Metal-free Synthesis of Cyclic Di-oxoguanidines via One-pot Sequential Transformation of Amines, Carbodiimides and Acyl Dichlorides″. Org. Biomol. Chem. 2012, 10, 6266–6270. (Inside Front Cover) 
  • 70. Weizhi Geng, Wen-Xiong Zhang, Wei Hao, Zhenfeng Xi*. ″Cyclopentadiene-Phosphine/Palladium Catalyzed Cleavage of C-N Bonds in Secondary    Amines: Synthesis of Pyrrole and Indole Derivatives from Secondary Amines and Alkenyl or Aryldibromides″. J. Am. Chem. Soc. 2012, 134, 20230-20233.  
  • 69. Lushan Zhou, and Wen-Xiong Zhang*. ″Practice and Thinking of Comprehensive Chemical Experiment Teaching for Undergraduates″. Huaxue Tongbao 2012, 75, 279-283. 
  • 68. Yi Zhou, Wen-Xiong Zhang, and Zhenfeng Xi*. ″1,3-Butadienylzinctrimer Formed via Transmetallation from 1,4-Dilithio-1,3-butadienes: Synthesis, Structural Characterization and Application in Negishi Cross-Coupling″. Organometallics 2012, 31, 5546–5550. 
  • 67.  Tianhao Meng, Wen-Xiong Zhang, Hui-Jun Zhang, Yun Liang, and Zhenfeng Xi*. ″Pd-Catalyzed Intermolecular Tandem Reaction of gem-Dibromoenynes with Anilines: A One-Pot Synthesis of Quinolines and Quinolinones″. Synthesis 2012, 44, 2754–2762. 
  • 66. Shaoguang Zhang, Junnian Wei, Ming Zhan, Qian Luo, Chao Wang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″2,6-Diazasemibullvalenes: Synthesis, Structural Characterization, Reaction Chemistry and Theoretical Analysis″. J. Am. Chem. Soc. 2012, 134, 11964–11967. 
  • 65. Heng Li, Lantao Liu, Fei Zhao, Congyang Wang, Chao Wang, Qiuling Song, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Carbonylation of 1-Lithiobutadiene with Carbon Monoxide Followed by Intramolecular Acyllithiation of C=C Double Bond and Intermolecular Acylation with Acid Chloride: Scope, Applications and Mechanistic Aspects″. J. Org. Chem. 2012, 77, 4793–4800. 
  • 64. Weizhi Geng, Hanliu Wang, Zitao Wang, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Synthesis Benzothieno[2,3-b]thiophenes, [2,3-b:3,2-d]-dithienothiophenes and Their Selenium Derivatives via Electrophilic Cyclization and McMurry Cyclization″. Tetrahedron 2012, 68, 5283–5289.

 

 2011

  • 63. Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi.* ″Zirconocene and Si-tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis″.Acc. Chem. Res.2011, 44, 541-551.
  • 62. Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*. ″Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation″. Angew. Chem. Int. Ed. 2011, 50, 8122 - 8126. 
  • 61. Wen-Xiong Zhang, Zitao Wang, Masayoshi Nishiura, Zhenfeng Xi*, and Zhaomin Hou*. ″Ln4(CH2)4-Cubane-Type Rare-Earth Methylidene Complexes Consisting of “(C5Me4SiMe3)LnCH2” Units (Ln = Tm, Lu) ″. J. Am. Chem. Soc. 2011, 133, 5712 - 5715. 
  • 60. Dongzhen Li, Yang Wang, Wen-Xiong Zhang*, Shaoguang Zhang, Jie Guang, and Zhenfeng Xi*. ″One-pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides and Zn(OTf)2″. Organometallics 2011, 30, 5278 – 5283. 
  • 59. Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang,* and Zhenfeng Xi*. ″Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile″. Organometallics 2011, 30, 3464 – 3467. 
  • 58. Shaoguang Zhang, Wen-Xiong Zhang, Jing Zhao, and Zhenfeng Xi*. ″One-pot Selective Synthesis of 5-Azaindoles via Zirconocene-Mediated Multi-Component Reactions of Three Different Organonitriles and One Alkyne″. Chem. Eur. J. 2011, 17, 2442 - 2449. 
  • 57. Zitao Wang, Weizhi Geng, Hanliu Wang, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Synthesis of Benzothiophenes Derivatives from Dilithio Reagents, Sulfur, and Electrophiles via Electrophilic Cyclization″. Tetrahedron Lett. 2011, 52, 6997 – 6999. 
  • 56. Shaoguang Zhang, Jing Zhao, Wen-Xiong Zhang, and Zhenfeng Xi*. ″One-pot Synthesis of Pyrrolo[3,2-d]pyridazines and Pyrrole-2,3-diones via Zirconocene-mediated Four-component Coupling of Si-tethered Diyne, Nitriles and Azide″.Org. Lett. 2011, 13, 1626 - 1629.
  • 55. Heng Li, Lantao Liu, Zitao Wang, Fei Zhao, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Iterative Dianion Relay Along the Ring: Formation of gem-Bis(trimethylsilyl) Cyclopentenones from 2,5-Bis(trimethylsilyl) Oxy-cyclopentadienyl Dianions and Acid Chlorides″. Chem. Eur. J. 2011, 17,7399 - 7403. 

 

2010

  • 54. Dongzhen Li, Jie Guang, Wen-Xiong Zhang*, Yang Wang, and Zhenfeng Xi*. ″Zn(OTf)2-Catalyzed Addition of Amines to Carbodiimides: Efficient Synthesis of Guanidines and Unpredicted Formation of Zn–N Amido Species″.Org. Biomol. Chem. 2010, 8, 1816 – 1820.
  • 53. Lantao Liu, Wen-Xiong Zhang*, Qian Luo, Heng Li, and Zhenfeng Xi*. ″Isolation and X-ray Structure of a Trimeric 1,4-Dilithio-1,3-butadiene and a Dimeric Me3Si-Substituted 1,4-Dilithio-1,3-butadiene″. Organometallics 2010, 29, 278 – 281.
  • 52. Zhongping Jiang, Zuo Xiao, Gaihong Zhang, Liangbing Gan*, Dian Wang, Wen-Xiong Zhang*.″Fullerenyl Azide: Synthesis and Reactivity″. Tetrahedron Lett. 2010, 51, 415 – 417.
  • 51. Shaoguang Zhang, Wen-Xiong Zhang, Jing Zhao, and Zhenfeng Xi*. ″Cleavage and Re-organization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds″. J. Am. Chem. Soc. 2010, 132, 14042 - 14045.
  • 50. Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Efficient One-Pot Synthesis of N-Containing Heterocycles by Multicomponent Coupling of Silicon-Tethered Diynes, Nitriles, and Isocyanides through Intramolecular Cyclization of Iminoacyl-Zr Intermediates″. Chem. Eur. J. 2010, 16,8419 - 8426. (VIP Highlight)
  • 49. Qifeng Wang, Wen-Xiong Zhang, Chen Lin, and Zhenfeng Xi*. ″Advances in the Synthesis and Reactivity of 2-Pyranylidene Carbene Complexes″. Chinese. Sci. Bull. 2010, 55, 2915 - 2923.
  • 48. Qian Luo, Chao Wang, Li Gu, Wen-Xiong Zhang, and Zhenfeng Xi*. ″Formation of a-Lithio Siloles from Silylated 1,4-Dilithio-1,3-butadienes: Mechanism and Applications″. Chem. Asian. J. 2010 , 5, 1120-112 8.

 

2009

 

  • 47. Zitao Wang, Yang Wang, Wen-Xiong Zhang,* Zhaomin Hou, and Zhenfeng Xi*. "Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones Via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur and Carbodiimides". J. Am. Chem. Soc. 2009, 131, 15108-15109. 
  • 46. Wen-Xiong Zhang, Shaoguang Zhang, Xiaohua Sun, Masayoshi Nishiura, Zhaomin Hou,* and Zhenfeng Xi*. "Isolation and Application of Unpredicted Three-ring-fused Zr/Si Intermediates in Zirconocene-mediated Intermolecular Coupling Reaction". Angew. Chem. Int. Ed. 2009, 48, 7277-7231.
  • 45. Wen-Xiong Zhang,* Dongzhen Li, Zitao Wang, and Zhenfeng Xi*. " Alkyl Aluminum Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substituted Guanidines". Organometallics 2009, 28, 882-887.
  • 44. Jiayao Yao, Zuo Xiao, Jianxin Zhang, Xiaobing Yang, Liangbing Gan*, and Wen-Xiong Zhang*. " Switched  Role of Fullerence in Diels-Alder Reaction: Facile Addition of Dienophiles to Conjugated Fullerene Diene Moiety". Chem. Commun. 2009, 401-403. (Cover Picture)
  • 43. Wen-Xiong Zhang, and Zhenfeng Xi*. "1-Lithio-1,3--dienes as Useful Building Blocks in Organic Synthesis". Pure Appl. Chem. 2009, 81, 235-246. (Review)
  • 42. Lantao Liu, Wen-Xiong Zhang, Chao Wang, Congyang Wang, and Zhenfeng Xi*. "Isolation, Structural Characterization and Synthetic Application of Oxy-cyclopentadienyl Dianions". Angew. Chem. Int. Ed. 2009, 48, 8111-8114.
  • 41. Shaoguang Zhang, Xiaohua Sun, Wen-Xiong Zhang, and Zhenfeng Xi*. " One-pot Multi-Component Synthesis of Azaindoles and Pyrroles from One Molecule of Si-Tethered Diyne and Three or Two Molecules of Organonitriles Mediated by Zirconocence". Chem. Eur. J. 2009, 15, 12608-12617.
  • 40. Chao Wang, Liang Deng, Jun Yan, Hailin Wang, Qian Luo, Wen-Xiong Zhang, and Zhenfeng Xi*. "Zirconocene-Mediated Ligand-Switched Selective Cleavage of Active and Inert Carbon-Carbon Bonds in Allylcyclopropanes".  Chem. Commun. 2009, 4414-4416.
  • 39. Toshiaki, Suzuki, Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Recent Progress in Half-sandwich Rare-earth-catalyzed Organic Synthesis".  J. Syn. Org. Chem. Jpn. 2009, 67, 451-464. (Review)
  • 38. Junhui Liu, Wen-Xiong Zhang, and Zhenfeng Xi*. "Synthesis and Reactivity of Four-membered Silacycles".  Chin. J. Org. Chem. 2009, 29, 491-503.
  • 37. Shaoguang Zhang, Junhui Liu, Wen-Xiong Zhang, and Zhenfeng Xi*. " Reactivity of Six-Membered Silacycles". Progress in Chemistry 2009, 21, 1487-1493. (Review)
  • 36. Junhui Liu, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*. "Synthesis of Six-Membered Silacycles". Progress in Chemistry 2009, 21, 1475-1486. (Review)
  • 35. Fei Zhao, Chao Wang, Lantao Liu, Wen-Xiong Zhang,  and Zhenfeng Xi*. "Skeletal Rearrangement of All-carbon Spiro Skeletons Mediated by Lewis Acid". Chem. Commun. 2009, 6569-6571.
  • 34. Qifeng Wang, Lantao Liu, Chen Lin, Hui Sun, Wen-Xiong Zhang, and Zhenfeng Xi*. "Hydride-Induced Cleavage of C-O Bond in Pyran Ring of 2-Pyranylidene Carbene Complexes Followed by Ring Closure of Unsaturated Acylmetalates and Reductive Elimination: Mechanism and Synthetic Application". Dalton Trans. 2009, 10433-10435.
  • 33. Xia Zhao, Zhenzhen Zhong, Lingling Peng, Wen-Xiong Zhang, and Jianbo Wang*. "Au(PPh3)Cl–AgSbF6-Catalyzed Rearrangement of Propargylic 1,3-Dithianes: Formation of 8-Membered 1,3-Bisthio-substituted Cyclic Allenes".  Chem. Commun. 2009, 2535-2537. 
  • 32. Li-Cheng Song,* Guo-Xia Jin, Li-Qun Zhao, Hu-Ting Wang, Wen-Xiong Zhang, and Qing-Mei Hu. "Self-Assembled Transition-Metal Macrocycles and Two-Dimensional Coordination Polymers Derived from Flexible C2Co2 Cluster-Bridged Bipyridine Ligands (4-C5H5NCO2CH2)2C2Co2(CO)6 and (3-C5H5NCO2CH2)2C2Co2(CO)6."  Eur. J. Inorg. Chem. 2009, 419-428.
  • 31. Qian Luo, Li Gu, Chao Wang, Junhui Liu, Wen-Xiong Zhang, and Zhenfeng Xi*. "Synthesis of Functionalized Siloles from Si-tethered Diynes". Tetrahedron Lett. 2009, 50, 3213-3215. 
  • 30. Junhui Liu, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*.  "Star-shaped Silacyclobutene-Containing π-Systems: Synthesis and Optical Properties". Organometallics 2009, 28, 413-417.

 

 2008

 

  • 29. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes". Angew. Chem. Int. Ed. 2008, 47, 9700-9703. (Highlighted by Synfacts and Riken Research)
  • 28. Wen-Xiong Zhang, Masayoshi Nishiura, Tomohiro Mashiko, and Zhaomin Hou*. "Half-Sandwich o-N,N-Dimethylaminobenzyl Complexes over the Full Size Range of Group 3 and Lanthanide Metals. Synthesis, Structural Characterization, and Catalysis of Phosphine P-H Bond Addition to Carbodiimides". Chem. Eur. J. 2008, 14, 2167-2179. (VIP Highlight)
  •  27. Zhenfeng Xi*, and Wen-Xiong Zhang*. "Synthetic Methods for Multiply Substituted Butadiene-containing Building Blocks". Synlett 2008, 2557-2570. (Account)
  • 26. Wen-Xiong Zhang, and Zhaomin Hou*. "Catalytic Addition of Alkyne C-H, Amine N-H, and Phosphine P-H Bonds to Carbodiimides: An Efficient Route to Propiolamidines, Guanidines, and Phosphaguanidines". Org. Biomol. Chem. 2008, 6, 1720-1730. (Perspective Article, Inside Cover Picture)
  • 25. Dongzhen Li, An Shi, Wen-Xiong Zhang,  Guangzhen Liu, and Zhenfeng Xi*. "Selective Synthesis of Multiply Substituted 7-Norbornenone Derivatives or Diels-Alder Cycloadducts from 1,2,3,4-Tetra-substituted 1,3-butadienes and Maleic Anhydride with or without Lewis Acids". Tetrahedron 2008, 64, 9895-9900.
  • 24. Qifeng Wang, Wen-Xiong Zhang, and Zhenfeng Xi*. "Pyranylidene Carbene Complexes from 1-Lithio-1,3-Dienes and M(CO)6 (M = Cr, Mo, W): Novel Synthesis and De-metallation Reaction". Organometallics 2008, 27, 3627-3629.
  • 23. Nan Yu, Congyang Wang, Fei Zhao, Lantao Liu, Wen-Xiong Zhang, and Zhenfeng Xi*. "Diversified Reaction Chemistry of 1,4-Dilithio-1,3-dienes with Nitriles: Facile Access to Tricyclic D1-Bipyrrolines, Multi-Substituted Pyridines, Siloles and (Z, Z)-Dienylsilanes by Tuning of Substituents on the Butadienyl Skeleton". Chem. Eur. J. 2008, 14, 5670-5679.
  • 22. Qian Luo, Chao Wang, Wen-Xiong Zhang, and Zhenfeng Xi*. "CuCl-Mediated Tandem CO Insertion and Annulation of 1,4-Dilithio-1,3-dienes: Formation of Multiply Substituted Cyclopentadienones and/or Their Head-to-head Dimers".  Chem. Commun. 2008, 1593-1595.

     

2007

  • 21. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Catalytic Addition of Amine N–H Bonds to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through Amine Protonolysis of Rare Earth Metal Guanidinates". Chem. Eur. J. 2007, 13, 4307-4051.
  • 20. Junhui Liu, Wen-Xiong Zhang, Xiangyu Guo, Zhaomin Hou,* and Zhenfeng Xi*. "Isolation and Synthetic Application of 2,5-Bis(alkynylsilyl) Zirconacyclopentadienes". Organometallics 2007, 26, 6812-6820.

 

 

2006

  • 19. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Alkali-Metal-Catalyzed Addition of Primary and Secondary Phosphines to Carbodiimides. A General and Efficient Route to Substituted Phosphaguanidines". Chem. Commun. 2006, 3812-3814.
  • 18. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Catalytic Addition of Secondary Amines to Carbodiimides by a Half-Sandwich Yttrium Complex: An Efficient Route to N,N’,N’’,N’’’-Tetrasubstituted Guanidines". Synlett 2006, 1213-1216. (Special Issue)

 

2005

  • 17. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes". J. Am. Chem. Soc. 2005, 127, 16788-16789.
  • 16. Zhenfeng Xi*, Wen-Xiong Zhang, Zhiyi Song, Weixin Zheng, Fanzhi Kong, and Tamotsu Takahashi*."Preparation of Vinyl Allenes from 1-Lithio-1,3-Butadienyl Phosphine Oxides and Aldehydes by the Wittig-Horner Reaction". J. Org. Chem. 2005, 70, 8785-8789.
  • 15. Jiang Lu, Guoliang Mao, Wen-Xiong Zhang, and Zhenfeng Xi*. "Lewis Acid- promoted Reactions of Zirconacyclopentadienes with Isocyanates. A One-pot Three-component Synthesis of Multiply-substituted Iminocyclopentadienes from One Isocyanate and Two Alkynes". Chem. Commun. 2005, 4848-4850.
  • 14. Zhenfeng Xi*, Fanzhi, Kong, Weixin Zheng, and Wen-Xiong Zhang. "Tearing a Cyclopentadienyl Ligand into Two Pieces: Cp is not only a ‘Spectator’". Chin. J. Org. Chem. 2005, 25, 229-233. 
  • 13. Li-Cheng Song*, Guo-Xia Jin, Wen-Xiong Zhang, and Qing-Mei Hu. "Cationic M(II)/Co(0) (M = Pd, Pt) Metallomacrocycles Containing Tetrahedral Co2C2 Cluster Cores Formed by Self-Assembly of Cluster-Bridged Bipyridine (4-C5H4NCO2CH2)2C2Co2(CO)6 and Diarsine-Chelated Complex Pd(dpab)(H2O)(OTf)][OTf] or [Pt(dpab)(H2O)2][OTf]2". Organometallics 2005, 24, 700-706.
  • 12. Li-Cheng Song*, Guo-Xia Jin, Hu-Ting Wang, Wen-Xiong Zhang, and Qing-Mei Hu. "Self-assembly of Cationic Pd(II)/Pt(II) Metallomacrocycles Containing Tetrahedral C2Co2 Clusters from Rigid Cluster-Bridged Bipyridine (4-C5H4N)2C2Co2(CO)6 and Diphosphine- or Diarsine-Chelated Pd(II)/Pt(II) Complexes [M(dppb)(H2O)2][OTf]2 (M = Pd, Pt), Pd(dpab)(H2O)(OTf)][OTf] and [Pt(dpab)(H2O)2][OTf]2". Organometallics 2005, 24, 6464-6471.
  • 11. Li-Cheng Song*, Guo-Xia Jin, Wen-Xiong Zhang, and Qing-Mei Hu. "Synthesis and Structural Characterization of Three Novel Macrocyclic Coordination Complexes Formed by Self-assembly of Bridged Bi- or Tetrapyridine with Transition Metal Salts". Chin. J. Chem. 2005, 23, 1065-1070.

 

 

2004

  • 10. Zhenfeng Xi*, Wen-Xiong Zhang, and Tamotsu Takahashi*. "Selective Preparation of 1,3-Butadienyl Phosphines, 1-Iodo- and 1,4-Diiodo- Butadienyl Phosphine Oxides via Zirconocene-Mediated Cross-coupling of Alkynylphosphines". Tetrahedron Lett. 2004, 45, 2427-2429.
  • 9.  Wen-Xiong Zhang, Weixin Zheng, Fanzhi, Kong, and Zhenfeng Xi*. "Novel Synthetic Methodologies of 1H-Phosphole Mediated by Organometallic Compounds". Chin. J. Org. Chem. 2004, 24, 1323-1331.
  • 8.  Weixin Zheng, Wen-Xiong Zhang, and Zhenfeng Xi*. "Cleavage of Chemical Bonds via b-Elimination Reaction of Organometallic Compounds". Chin. J. Org. Chem. 2004, 24, 1489-1500.
  • 7.  Li-Cheng Song*, Wen-Xiong Zhang, Qing-Mei Hu, and Li-Qun Zhao. "Synthesis and Characterization of a Novel Bicyclic Dimer [CuBr(pcadgd)]2 Formed via Self-assembly of 4-Pyridinecarboxylic Acid Diethylene Glycol Diester (pcadgd) with Copper(I) Bromide". Transit. Met. Chem. 2004, 29, 603-606.

  

 

 2002

  • 6. Li-Cheng Song*, Wen-Xiong Zhang, Jin-You Wang, and Qing-Mei Hu. "Two Novel One-dimensional Coordination Polymers [Cu2(m-Br)2(pcaede)2ּ2H2O]n and [Cu2(m-Br)2(pcaede)2ּ0.5THFּ0.5H2O]nFormed via Self-assembly of 4-Pyridinecarboxylic Acid 1,2-Ethyanediyl Ester (pcaede) with Copper(I) Bromide". Transit. Met. Chem. 2002, 27, 526-531. 
  • 5.  Li-Cheng Song*, Wen-Xiong Zhang, and Qing-Mei Hu. "Syntheses and Characterizations of Novel One-dimensional Coordination Polymers Self-assembling from Co(NCS)2 and Flexible Diester Bridged Pyridine-based Ligands". Chin. J. Chem. 2002, 20, 1421-1429.

 

2000

  • 4. Wen-Xiong Zhang, Hong Liang, Hai-Cuo Qin, and Wen-Bang Huang. "Separation, purification and structural analysis of acid heteropolysaccharides from Spirulina Platensis". Zhong CaoYao 2000, 31, 326-328.

 

1999

  • 3. Wen-Xiong Zhang, Hong Liang, Hai-Cuo Qin, and Wen-Bang Huang. "Study on the extraction of phycocyanobilin from Spirulina Platensis". Jingxi Huagong 1999, 16, 40-42.
  • 2. Wen-Xiong Zhang, Hong Liang, Hai-Cuo Qin, and Wen-Bang Huang. "Research and development of the pharmaceutical composition of Spirulina Platensis". Tianran Chanwu Yanjiu yu Kaifa 1999, 11, 75-80.
  • 1. Wen-Xiong Zhang, Hai-Cuo Qin, Wen-Bang Huang, Hong Liang, and Shan-Dong Wei. "Study on technology of extracting crude polysacchride from Spirulina Platensis".   Guangxi Huagong 1999, 28, 11-14.