箴言
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在科学上没有平坦的大道,只有那些不畏艰险沿着陡峭山路攀登的人,才有希望达到光辉的顶点。
----马克思
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合作研究
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请有兴趣的研究组联系我们。欢迎任何形式的合作，尤其是在自组装、水凝胶以及生物医药等方向的合作。
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请有兴趣的研究组联系我们。欢迎任何形式的合作，尤其是在自组装、水凝胶以及生物医药等方向的合作。
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研究成果
58. Precision Synthesis of Macrocyclic Giant Surfactants Tethered with Two Different Polyhedral Oligomeric Silsesquioxanes at Distinct Ring Locations via Four Consecutive “Click” Reactions. Polym. Chem. 2015, 6, 827-837
发布时间:2016-04-27
Li, Y.; Su, H.; Feng, X.; Yue, K.; Wang, Z.; Lin, Z.; Zhu, X.; Fu, Q.; Zhang, Z.;* Cheng, S. Z. D.;* Zhang, W.-B.* Precision Synthesis of Macrocyclic Giant Surfactants Tethered with Two Different Polyhedral Oligomeric Silsesquioxanes at Distinct Ring Locations via Four Consecutive “Click” Reactions. Polym. Chem. 2015, 6, 827-837. [Link] [PDF]
Abstract
The combined utilization of chemoselective “click” chemistry allows for the preparation of well-defined macromolecules with complex compositions and architectures. In this article, we employed the sequential “click” strategy to further expand the scope of synthetically available giant molecules by precisely constructing new giant surfactants based on polyhedral oligomeric silsesquioxane (POSS) tethered cyclic polymers. The general synthetic approach involves sequentially performed strain-promoted azide–alkyne cycloaddition (SPAAC) as a method for bimolecular homobifunctional ring closure, copper-catalyzed azide–alkyne cycloaddition (CuAAC) for POSS-polymer conjugation, and thiol–Michael/thiol–ene reactions for POSS surface functionalization. Specifically, a cyclic polymer tethered with two POSS cages of distinct surface chemistry at different locations of the chain has been prepared. This work promises to afford numerous cyclic polymers-based giant surfactants with diverse structural variations for further investigation on unexpected physical properties.
Abstract
The combined utilization of chemoselective “click” chemistry allows for the preparation of well-defined macromolecules with complex compositions and architectures. In this article, we employed the sequential “click” strategy to further expand the scope of synthetically available giant molecules by precisely constructing new giant surfactants based on polyhedral oligomeric silsesquioxane (POSS) tethered cyclic polymers. The general synthetic approach involves sequentially performed strain-promoted azide–alkyne cycloaddition (SPAAC) as a method for bimolecular homobifunctional ring closure, copper-catalyzed azide–alkyne cycloaddition (CuAAC) for POSS-polymer conjugation, and thiol–Michael/thiol–ene reactions for POSS surface functionalization. Specifically, a cyclic polymer tethered with two POSS cages of distinct surface chemistry at different locations of the chain has been prepared. This work promises to afford numerous cyclic polymers-based giant surfactants with diverse structural variations for further investigation on unexpected physical properties.