张文雄

博士,教授,博士生导师


研究方向:稀土金属有机化学和有机合成化学


电话:010-6275-8294
传真:010-6275-1708
电子信箱:wx_zhang@pku.edu.cn
 
         
 


教育和工作经历:

2016.8 - 至今, 北京大学化学学院 教授
2009.10 - 2009.12, 日本理化学研究所 客座研究员
2007.10 - 2016.7, 北京大学化学学院 副教授
2004.11 - 2007.9, 日本理化学研究所 协力研究员
2004.1 - 2004.3, 日本北海道大学JST 研究员
2002.10 - 2004.10, 北京大学化学学院 博士后
2003.1, 获南开大学理学博士学位
1999.6, 获广西师范大学理学硕士学位
1996.7, 获湖南师范大学化学教育学士学位

 
 


主讲课程:

合成化学 II
金属有机化学

 
 


获奖情况:

2017年获国家杰出青年科学基金
2015年获Thieme Chemistry Journals Award

 
 


研究领域和兴趣:

稀土金属有机杂环试剂的设计、合成及反应性研究;金属催化的碳-氮键活化;基于碳二亚胺分子的化学键活化、形成新反应构建含氮杂环化合物。在研究过程中,秉承“基于机理和金属有机活性中间体的合成化学”研究理念,不仅注重新反应的发现和发展,更注重通过对反应机理的理解和认识,有目的地发现新反应。

 
         
 


代表性论文

  • Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang.* "Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes". Angew. Chem. Int. Ed. 2017, 56, 15886-15890.
  • Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation". J. Am. Chem. Soc. 2017, 139, 13688-13691.
  • Baosheng Wei, Liang Liu, Wen-Xiong Zhang,* and Zhenfeng Xi. "Synthesis and Structural Characterization of Butadienyl Calcium-based Heavy Grignard Reagents and Ca4[O] Inverse Crown Ether Complex". Angew. Chem. Int. Ed. 2017, 56, 9188-9192.
  • Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi. "Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes". Chem. Sci. 2017, 8, 6852-6856.
  • Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Spiro Metallaaromatics of Pd, Pt, Rh: Synthesis and Characterization". J. Am. Chem. Soc. 2017, 139, 5039-5042.
  • Wangyang Ma, Chao Yu, Tianyang Chen, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi. "Metallacyclopentadienes: Synthesis, Structure and Reactivity". Chem. Soc. Rev. 2017, 46, 1160-1192.
  • Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts". Angew. Chem. Int. Ed. 2016, 55, 14762–14765.
  • Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang,* and Zhenfeng Xi. "Direct Synthesis of Phospholyl Lithium from White Phosphorus". Angew. Chem. Int. Ed. 2016, 55, 9187–9190.
  • Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang,* and Zhenfeng Xi. "Transition-Metal-Catalyzed Cleavage of C–N Single Bonds". Chem. Rev. 2015, 115, 12045-12090.
  • Yang Wang, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides". J. Am. Chem. Soc. 2012, 134, 2926-2929.
  • Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi.* "Zirconocene and Si-tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis". Acc. Chem. Res. 2011, 44, 541-551.
  • Yang Wang, Wen-Xiong Zhang,* Zitao Wang, and Zhenfeng Xi.* "Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and Their Selenium and Tellurium Derivatives by Convergent Tandem Annulation". Angew. Chem. Int. Ed. 2011, 50, 8122-8126.
  • Zitao Wang, Yang Wang, Wen-Xiong Zhang,* Zhaomin Hou, and Zhenfeng Xi.* "Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur and Carbodiimides". J. Am. Chem. Soc. 2009, 131, 15108–15109.  
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