本组成员: 邓桂胜 博士后 (2000.10 ~ 2002.9) Email: gsdeng@pku.edu.cn 邓桂胜博士2000年时候加入本组进行博士后研究。他的主要工作是发展经由a-重氮羰基化合物的新的合成方法。他发展了路易斯酸控制的 Ti(IV)-烯醇化物对a,b-不饱和羰基化合物的区域选择性加成，他的这部分工作发表在 Angew. Chem.上。此外，他还发展了基于重氮在Rh(II)催化下分解的新的合成吡咯衍生物的方法。现在邓桂胜博士在湖南师范大学工作。 Current position: Hunan Normal University (Email: gsdeng@hunnu.edu.cn)

在本组期间发表的论文:

(1) Lewis Acids Controlled Regioselective 1,2 and 1,4 Reaction of a, b-Unsaturated Carbonyl Compounds with Ti(IV) Enolates Derived from a-Diazo-b-ketocarbonyl Compounds
Guisheng Deng, Xue Tian, Zhaohui Qu and Jianbo Wang, Angew. Chem. Int. Ed. Engl. 2002, 41, 2773-2776. 查看

(2) Rh2(OAc)4-Mediated Diazo Decomposition of d-(N-Tosyl)amino-b-keto-a-diazo Carbonyl Compounds: An Novel Approach to Pyrrole Derivatives
Guisheng Deng, Nan Jiang, Zhihua Ma, Jianbo Wang, Synlett, 2002, 1913-1915. 查看

(3) A Novel Approach to Two-ring Fused Cyclopentenone Derivatives
Guisheng Deng, Xue Tian and Jianbo Wang, Tetrahedron Lett. 2003, 44(3), 587-589. 查看

(4) Study on the Mass Spectrometry of Diazo Compounds
Zhenpei Yu, Xiaoranhe, Guisheng Deng and Jianbo Wang, J. Inst. Anal. 2003, 22, Suppl. 125.

(5) Regioselective 1, 2-Addition of Ti(IV)-Enolate to alpha, beta–Unsaturated Compounds
Guisheng Deng, Mingyi Liao, Xue Tian, Jianbo Wang
Chin. Chem. Lett. 2005, 16, 589-592. 查看

(6) New Approaches to Polysubstituted Pyrroles and g-Lactams based on Nucleophilic Addition of Ti(IV) Enolates Derived from a-Diazo-b-keto Carbonyl Compounds to N-Tosylimines
Changqing Dong, Guisheng Deng and Jianbo Wang
J. Org. Chem. 2006, 71, 5560-5564.

(7) Synthesis of Oxygen-containing Heterocyclic Compounds Based on the Intramolecular O-H Insertion and Wolff Rearrangement of a–Diazocarbonyl Compounds
Mingyi Liao, Suwei Dong, Guisheng Deng, Jianbo Wang
Tetrahedron Lett. 2006, 47, 3927-3929.

(8) Cu(I)-Catalyzed Coupling of Diaryldiazomethanes with Terminal Alkynes: An Efficient Synthesis of Tri-Aryl-Substituted Allenes
Chenggui Wu, Fangdong Hu, Zhenxing Liu, Guisheng Deng, Fei Ye, Yan Zhang, Jianbo Wang
Tetrahedron 2015, 71, accepted.