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Lei Jiao

Graduate Students(2005.9~ )
Email: Leijiao@yeah.net
tel: 010-62752612

1983.1 Born in Beijing


Education:
2005.9 ~ present: Institue of Organic Chemistry, College of Chemistry and Molecular 
Engineering, Peking University. Advisor: Professor Zh-Xiang Yu

2001.9 ~2005.7: Department of Chemistry, College of Chemistry and Molecula Engineering, Peking University. Advisor: Professor Jiaxi Xu

Honors and Awards: 
2005.11: The 9th Tiaozhanbei National Contest of Science and Technology

2006.11: Der Scholarship

2006.11: Creative Award, Peking University

2008.112008 Roche Creative Chemistry Award

Publications: 

1, Rh(I)-Catalyzed [(3 + 2) + 1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson−Khand Reaction and Total Synthesis of (±)-α-Agarofuran Lei Jiao, Mu Lin, Lian-Gang Zhuo and Zhi-Xiang Yu. Org. Lett.201012 ,2528–2531

2, Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes Lei Jiao, Mu Lin and Zhi-Xiang Yu Chem. Commun.201046, 1059 - 1061

3. Rh(I)-Catalyzed Intramolecular [3+2] Cycloaddition of trans-Vinylcycloproplane-Enes. Jiao, L.; Ye, S.; Yu, Z.-X.* Journal of the American Chemical Society 2008130, 7178-7179.

4. Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton: Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin. Jiao, L.; Yuan, C.; Yu, Z.-X.* Journal of the American Chemical Society 2008130, 4421-4430.

5. Synthesis and Stereochemistry of 3-(Thiophen-2-yl)-β-Lactams. Li, B.; Liang, Y.; Jiao, L.; Hu, L.; Du, D.; Xu, J.* Acta Chimica Sinica 200765, 1643-1648.

6Mechanistic Twist of the [8+2] Cycloadditions of Dienylisobenzofurans and Dimethyl Acetylenedicarboxylate: Stepwise [8+2] versus [4+2]/[1,5]-Vinyl Shift Mechanisms Revealed through a Theoretical and Experimental Study.Chen, Y.; Ye, S.; Jiao, L.; Liang, Y.; Sinha-Mahapatra, D. K.; Herndon, J. W.; Yu, Z.-X.* Journal of the American Chemical Society 2007129, 10773-10784.

7A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-Vinylcyclopropanes and CO for the Synthesis of Cyclooctenones.Wang, Y.; Wang, J.; Su, J.; Huang, F.; Jiao, L.; Liang, Y.; Yang, D.; Zhang, S.; Wender, P. A.; Yu, Z.-X.* Journal of the American Chemical Society 2007129, 10060-10061.

8An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine-Catalyzed (3+2) Cycloaddition of Allenoates and Alkenes. Xia, Y.; Liang, Y.; Chen, Y.; Wang, M.; Jiao, L.; Huang, F.; Liu, S.; Li, Y.; Yu, Z.-X.* Journal of the American Chemical Society 2007129, 3470-3471.

9Nitrene Equivalent Mediated Metal-Free Ring Expansions of Alkylidenecyclopropanes and an Alkylidenecyclobutane. Liang, Y.; Jiao, L.; Wang, Y.; Chen, Y.; Ma, L.; Xu, J.; Zhang, S.; Yu, Z.-X.* Organic Letters 20068, 5877-5879.

10Do Reaction Conditions Affect the Stereoselectivity in the Staudinger Reaction? Wang, Y.; Liang, Y.; Jiao, L.; Du, D.; Xu, J.* Journal of Organic Chemistry 200671, 6983-6990.

11Origin of the Relative Stereoselectivity of the β-Lactam Formation in the Staudinger Reaction. Jiao, L.; Liang, Y.; Xu, J.* Journal of the American Chemical Society 2006128, 6060-6069.

12. Catalyst-Free, High-Yield, and Stereospecific Synthesis of 3-Phenylthio β-Lactam Derivatives. Jiao, L.; Liang, Y.; Zhang, Q.; Zhang, S.; Xu, J.* Synthesis 2006, 659-665.

13. A Versatile Method for the Synthesis of 3-Alkoxycarbonyl β-Lactam Derivatives. Jiao, L.; Zhang, Q.; Liang, Y.; Zhang, S.; Xu, J.* Journal of Organic Chemistry 200671, 815-818.

14. Reactions of Imidates with Phenoxyacetyl Chloride. Jiao, L.; Liang, Y.; Wu, C.; Huang, X.; Xu, J.* Chemical Research in Chinese Universities 200521, 59-64.

15. Microwave- and Photoirradiation-Induced Staudinger Reactions of Cyclic Imines and Ketenes Generated from α-Diazoketones. A Further Investigation Into the Stereochemical Process. Liang, Y.; Jiao, L.; Zhang, S.; Xu, J.* Journal of Organic Chemistry200570, 334-337.

 

Hobbies:
 badminton, travelling, and photograph