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Prof. Jianbo Wang

Dr. Yan Zhang

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Wgroup member: Di Qiu

Graduate student (2006~ 2015)

Current position: Tianjin Normal University;

Email: qiudi@pku.edu.cn

Education
University 2006.9 ~ 2015.7: study in Organic Chemistry, CCME, Peking University

B.Sc thesis: Studies on Gold-catalyzed Halogenations of Aryl Boronates
Ph.D thesis:
Some Basic Functional Groups Transformations of Aromatic Compounds

Publications

(1) Direct Conversion of Arylamines to the Pinacol Boronates: A Metal-Free Borylation Process
Fanyang Mo, Yubo Jiang, Di Qiu, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed.
2010, 49, 1846-1849. Click here. Selected by Editors as Hot Paper: Click here.

(2) Gold-Catalyzed Halogenation of Aromatics by N-Halosuccinimides
Fanyang Mo, Jerry Mingtao Yan, Di Qiu, Fei Li, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed.
2010, 49, 2028-2032. Click here.

(3) Enantioselective Synthesis of Condensed and Transannular Ring Skeletons Containing Pyrrolidine Moiety
Fanyang Mo, Fei Li, Di Qiu and Jianbo Wang
Tetrahedron
, 2010, 66, 1274-1279. Click here.

(4) Gold(III)-Catalyzed Halogenation of Aromatic Boronates with N-Halosuccinimides
Di Qiu, Fanyang Mo, Zhitong Zheng, Yan Zhang and Jianbo Wang
Org. Lett. 2010, 12, 5474-5477.

(5) A Base-Free, One-Pot Diazotization/Cross-Coupling of Anilines with Arylboronic Acids
Fanyang Mo, Di Qiu, Yubo Jiang, Yan Zhang and Jianbo Wang
Tetrahedron Lett. 2011, 52, 518-522.

(6) New Developments in Aromatic Halogenation, Borylation and Cyanation
Di Qiu, Fanyang Mo, Zhitong Zheng, Yan Zhang and Jianbo Wang
Chimia 2011, 65, 909-913.

(7) Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate
Di Qiu, Zhitong Zheng, Fanyang Mo, Qing Xiao, Yu Tian, Yan Zhang and Jianbo Wang
Org. Lett. 2011, 13, 4988-4991.

(8) Increments for 1H and 13C NMR Chemical Shifts in Pinacol Arylboronates
Di Qiu, Zhitong Zheng, Fanyang Mo, Yan Zhang and Jianbo Wang
Can. J. Chem. 2012, 90, 71-74.

(9) 1-Chloro-2,5-pyrrolidinedione, NCS
Di Qiu and Jianbo Wang
Encyclopedia of Reagents for Organic Synthesis (EROS), Second Update, 2012

(10) Studies Toward the Synthesis of (R)-(+)-Harmicine
Fanyang Mo, Fei Li, Di Qiu, Yan Zhang and Jianbo Wang
Chin. J. Chem. 2012, 30, 2297-2302.

(11) Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement
Yubo Jiang, Fanyang Mo, Di Qiu, Chunxiang Kuang, Yan Zhang and Jianbo Wang
Chin. J. Chem. 2012, 30, 2029-2035. (Invited contribution for a special issue)

(12) Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation
Di Qiu, Liang Jin, Zhitong Zheng, He Meng, Fanyang Mo, Xi Wang, Yan Zhang, and Jianbo Wang
J. Org. Chem. 2013, 78, 1923-1933. (JOC Most-Read Article in November 2012) (For Howard Zimmerman Memorial Issue)

(13) Synthesis of Aryltrimethylstannanes from Arylamines: A Sandmeyer-Type Stannylation Reaction
Di Qiu, He Meng, Liang Jin, Shuai Wang, Shengbo Tang, Xi Wang, Fanyang Mo, Yan Zhang* and Jianbo Wang*
Angew. Chem. Int. Ed. 2013, 52, 11581-11584.

(14) Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group
Xi Wang, Yan Xu, Fanyang Mo, Guojing Ji, Di Qiu, Jiajie Feng, Yuxuan Ye, Songnan Zhang,Yan Zhang and Jianbo Wang
J. Am. Chem. Soc. 2013, 135, 10330-10333. (JACS Most Read Articles in August, 2013)(Highlighted by Synfacts 2013, 9(10), 1113; Highlighted by Angew. Chem.)

(15) Synthesis of Arylboronic Pinacol Esters from Corresponding Arylamines
Di Qiu, He Meng, Liang Jin, Shengbo Tang, Shuai Wang, Fangyang Mo, Yan Zhang and Jianbo Wang (Checked by Austin Smith and Margaret Faul )
Org. Synth. 2014, 91, 106-105.

(16) Direct Synthesis of Arylboronic Pinacol Esters from Arylamines
Di Qiu, Yan Zhang and Jianbo Wang
Org. Chem. Front. 2014, 1, 422-425. (OCF Most-Read Article)

(17) Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions
Di Qiu, Shuai Wang, Shengbo Tang, He Meng, Liang Jin, Fanyang Mo, Yan Zhang and Jianbo Wang
J. Org. Chem. 2014, 79, 1979-1988. (JOC Most-Read Article)

(18) Synthesis, Structure and Reactivity of Anionic sp2-sp3 Diboron Compounds
Sabrina Pietsch, Emily C. Neeve, David C. Apperley, Rüdiger Bertermann, Fanyang Mo, Di Qiu, Man Sing Cheung, Li Dang, Jianbo Wang, Udo Radius, Zhenyang Lin,* Christian Kleeberg,* and Todd B. Marder*
Chem. Eur. J. 2015, 21, 7082-7099. (Hot Paper)

(19) Rh(I)-Catalyzed Stille-Type Coupling of Diazoesters with Aryl Trimethylstannanes
Zhen Liu, Ying Xia, Sheng Feng, Shuai Wang, Di Qiu, Yan Zhang, Jianbo Wang
Aust. J. Chem. 2015, 68, 1379-1384.

(20) Pd(0)-Catalyzed Carbene Insertion into Si-Si and Sn-Sn Bonds
Zhenxing Liu, Haochen Tan, Tianren Fu, Ying Xia, Di Qiu, Yan Zhang, Jianbo Wang
J. Am. Chem. Soc. 2015, 137, 12800-12803.

(21) Recent Advances in C(sp3)-H Bond Functionalization via Metal Carbene Insertions
Bo Wang, Di Qiu, Yan Zhang and Jianbo Wang
Beilstein J. Org. Chem. 2016, 12, 796-804. (Invited Contribution for "C–H Functionalization/Activation in Organic Synthesis as a Thematic Series")

(22) Nitrogen Group Retaining Reaction in the Transformation of Diazo Compounds
Di Qiu,* Menglong Qiu, Rong Ma, Yan Zhang and Jianbo Wang
Acta Chimica Sinica 2016, 74, 472-487.

(23) Metal-Free Aromatic Carbon-Phosphorus Bond Formation via a Sandmeyer-Type Reaction
Shuai Wang, Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang
J. Org. Chem. 2016, 81, 11603-11611. (Highlighted by Organic Chemistry Portal)

(24) Synthesis of Benzyltributylstannanes by the Reaction of N-Tosylhydrazones with Bu3SnH
Di Qiu, Shuai Wang, He Meng, Shengbo Tang, Yan Zhang, and Jianbo Wang
J. Org. Chem. 2017, 82, 624-632.

(25) Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions with N-Tosylhydrazones
Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang
Adv. Organomet. Chem. 2017, 67, 151-219. (An invited book chapter)

(26) Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion
Ying Xia, Di Qiu and Jianbo Wang
Chem. Rev. 2017, 117, 13810-13889.

(27) Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, CF3)
Fanyang Mo,* Di Qiu, Yan Zhang and Jianbo Wang*
Acc. Chem. Res. 2018, 51, 496-506.

 


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?2002 Wgroup, last updated April 12, 2018
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry
Peking University, Beijing 100871, P. R. China

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Email: wangjb@pku.edu.cn