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王剑波

有机化学,博士,长江特聘教授

 

电话:010-62757248
电子信箱:wangjb@pku.edu.cn
通讯地址:北京大学化学与分子工程学院 B429,北京 100871
课题组主页:http://old.chem.pku.edu.cn/physicalorganic/home.htm

教育及学术简历:

  • 2005-至今     北京大学化学学院长江特聘教授
  • 1999-至今     北京大学化学与分子工程学院,教授,博士生导师
  • 1995-1999     北京大学化学与分子工程学院,副教授
  • 1993-1995     威斯康星大学,博士后
  • 1990-1993     日内瓦大学,博士后
  • 1984-1990     北海道大学,硕士、博士
  • 1979-1983     南京理工大学,本科

主讲课程:

本科生专业必修课“有机化学(一)”;本科生专业任选课“物理有机化学”

研究领域和兴趣:

  • 过渡金属催化的卡宾转移反应、卡宾偶联以及基于卡宾的高分子聚合
  • 重氮化合物以及重氮盐类化合物的反应、含硼硅有机化合物的合成及反应
  • 有机化学中的基本官能团转化以及自由基反应等

代表性论文:

  1. Fanyang Mo, Di Qiu, Yan Zhang and Jianbo Wang, "Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, CF3)." Acc. Chem. Res. 2018, 51, 496-506.
  2. Ying Xia, Di Qiu and Jianbo Wang, "Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion." Chem. Rev. 2017, 117, 13810-13889.
  3. Zhikun Zhang, Zhe Sheng, Weizhi Yu, Guojiao Wu, Rui Zhang, Wen-Dao Chu, Yan Zhang and Jianbo Wang, "Catalytic Asymmetric Trifluoromethylthiolation via Enantioselective [2,3]-Sigmatropic Rearrangement of Sulfonium Ylides." Nature Chem. 2017, 9, 970-976.
  4. Wen-Dao Chu, Lei Zhang, Zhikun Zhang, Qi Zhou, Fanyang Mo, Yan Zhang, and Jianbo Wang, "Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes." J. Am. Chem. Soc. 2016, 138, 14558-14561.
  5. Zhenxing Liu, Haochen Tan, Tianren Fu, Ying Xia, Di Qiu, Yan Zhang, Jianbo Wang, "Pd(0)-Catalyzed Carbene Insertion into Si-Si and Sn-Sn Bonds." J. Am. Chem. Soc. 2015, 137, 12800-12803.
  6. Fei Ye, Shuanglin Qu, Lei Zhou, Cheng Peng, Chengpeng Wang, Jiajia Cheng, Mohammad Lokman Hossain, Yizhou Liu, Yan Zhang, Zhi-Xiang Wang, and Jianbo Wang, "Pd-Catalyzed C-H Functionalization of Acyldiazomethane and Tandem Cross-Coupling Reactions." J. Am. Chem. Soc. 2015, 137, 4435-4444.
  7. Ying Xia, Zhenxing Liu, Zhen Liu, Rui Ge, Fei Ye, Mohammad Hossain, Yan Zhang, Jianbo Wang, "Formal Carbene Insertion into C-C Bond: Rh(I)-Catalyzed Reaction of Benzocyclobutenols with Diazoesters." J. Am. Chem. Soc. 2014, 136, 3013-3015.
  8. Ying Xia, Shuanglin Qu, Qing Xiao, Zhi-Xiang Wang, Peiyuan Qu, Li Chen, Zhen Liu, Leiming Tian, Zhongxing Huang, Yan Zhang, Jianbo Wang, "Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene-Yne-Ketones as Carbene Precursors." J. Am. Chem. Soc. 2013, 135, 13502-13511.
  9. Xi Wang, Yan Xu, Fanyang Mo, Guojing Ji, Di Qiu, Jiajie Feng, Yuxuan Ye, Songnan Zhang, Yan Zhang and Jianbo Wang, "Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group." J. Am. Chem. Soc. 2013, 135, 10330-10333.
  10. Qing Xiao, Yan Zhang, Jianbo Wang, "Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions." Acc. Chem. Res. 2013, 46, 236-247.
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